辽宁红透山块状硫化物矿床蚀变带元素迁移特征及定量计算   总被引：2，自引：1，他引：1  

郑远川  顾连兴  汤晓茜  吴昌志  李春海  刘四海 《矿床地质》2010,29(5):785-809

辽宁红透山块状硫化物矿床（MSD）位于华北地台东北部的浑北花岗岩-绿岩地体内,矿区岩石在30～28 亿年期间受到了600～650℃的高级角闪岩相变质。研究结果表明,广泛分布于红透山层状矿体下盘数百米处的和直接产于矿体下盘的堇青-直闪片麻岩,分别代表了变质后的MSD成矿系统以绿泥石化为特征的半整合和筒状不整合海底热液蚀变带。微量元素特征显示,层状堇青-直闪片麻岩的原岩并非同一种岩石,而是由5种不同岩性的岩石组成,筒状堇青-直闪片麻岩的原岩主要由流纹质岩石组成,而在堇青-直闪片麻岩走向上与之过渡的角闪片麻岩和黑云片麻岩则代表了不同岩性蚀变岩的未蚀变原岩。质量变化计算表明,相对于未蚀变原岩而言,两种蚀变岩的成分发生了显著变化,其中层状堇青-直闪片麻岩的Fe、Mg发生了富集,Na、K、Ca、Cu、Pb和Zn等元素被迁出,而筒状堇青-直闪片麻岩的Fe、Mg、Si、Na、Pb、Cu和Zn等元素则发生了富集,K被迁出。重稀土元素（HREE）和高场强元素(Zr、Ti、Nb、Hf和Ta)在海底热液蚀变过程中保持惰性,而Rb、Sr、Ba和轻稀土元素（LREE,尤其是Eu）则被强烈的迁出。这些元素变化特征表明海底热液蚀变以绿泥石化和硅化为特征,同时海底水-岩反应体系具有高水/岩比值。层状堇青-直闪片麻岩可作为红透山矿区成矿潜力评价的重要依据,而含硫化物石英脉的筒状堇青-直闪片麻岩不但本身可成为工业矿体,还可作为上覆层状矿体的近矿找矿标志。  相似文献   

Formation of gold deposits: a metamorphic devolatilization model   总被引：5，自引：0，他引：5  

G. N. PHILLIPS  R. POWELL 《Journal of Metamorphic Geology》2010,28(6):689-718

A metamorphic devolatilization model can explain the enrichment, segregation, timing, distribution and character of many goldfields such as those found in Archean greenstone belts, slate‐belts and other gold‐only provinces. In this genetic model, hydrated and carbonated greenschist facies rocks, particularly metabasic rocks, are devolatilized primarily across the greenschist–amphibolite facies boundary in an orogenic setting. Devolatilization operates on the scale of individual mineral grains, extracting not just H₂O and CO₂ but also S and, in turn, Au. Elevated gold in solution is achieved by complexing with reduced S, and by H₂CO₃ weak acid buffering near the optimal fluid pH for gold solubility (the buffering is more important than being at the point of maximum gold solubility). Low salinity ensures low base metal concentrations in the auriferous metamorphic fluid. Migration of this fluid upwards is via shear zones and/or into hydraulic fracture zones in rocks of low tensile strength. The geometry of the shear zones dictates the kilometre‐scale fluid migration paths and the degree of fluid focusing into small enough volumes to form economic accumulations of gold. Deposition of gold from solution necessitates breakdown of the gold–thiosulphide complex and is especially facilitated by fluid reduction in contact with reduced carbon‐bearing host rocks and/or by sulphidation of wallrocks to generate iron‐bearing sulphide and precipitated gold. As such, black slate, carbon seams, banded iron formation, tholeiitic basalt, magnetite‐bearing diorite and differentiated tholeiitic dolerite sills are some of the important hosts to major goldfields. Gold deposition is accompanied by carbonation, sulphidation and muscovite/biotite alteration where the host rock is of suitable bulk composition. The correlation of major gold deposits with rock type, even when the gold is primarily in veins, argues for rock‐dominated depositional systems, not fluid‐dominated ones. As a consequence, a general role in gold deposition for fluid mixing, temperature decrease and/or fluid pressure decrease and boiling is unlikely, although such effects may be involved locally. Several geological features that are recorded at gold‐only deposits today reflect subsequent modifications superimposed upon the products of this generic metamorphic devolatilization process. Overprinting by higher‐grade metamorphism and deformation, and/or (palaeo)‐weathering may provide many of the most‐obvious features of goldfields including their mineralogy, geochemistry, geometry, small‐scale timing features, geophysical response and even mesoscopic gold distribution.  相似文献   

Paleoproterozoic gabbronoritic and granitic magmatism in the northern margin of the North China craton: Evidence of crust–mantle interaction     

Peng Peng  Jinghui Guo  Mingguo Zhai  Wouter Bleeker 《Precambrian Research》2010

Paleoproterozoic Xuwujia gabbronorites in the northern margin of the North China craton occur as dykes, sills and small plutons intruded into khondalite (aluminous paragneisses, sedimentary protoliths deposited at ca. 2.0–1.95 Ga), and as numerous entrained bodies and fragments of variable scales in the Liangcheng granitoids (ca. 1.93–1.89 Ga). These gabbronoritic dykes are present at all locations where ca. 1.93–1.92 Ga ultra-high-temperature metamorphism is recorded in the khondalite. A gabbronorite sample from the Hongmiaozi dyke gives zircon ²⁰⁷Pb/²⁰⁶Pb mean ages of 1954 ± 6 Ma (core domains) and 1925 ± 8 Ma (rim domains). These ages, as well as previously reported ages, constrain the age of mafic magmatism to be at ca. 1.96–1.92 Ga (∼1.93 Ga). One sample from the Xigou gabbro intruded by the Liangcheng granitoids gives a zircon ²⁰⁷Pb/²⁰⁶Pb mean age of 1857 ± 4 Ma, which is interpreted as the age of a metamorphic overprint. The Xuwujia gabbronorites comprise mainly gabbronorite compositions, as well as some norite, olivine gabbronorite, monzonorite, quartz gabbronorite, and quartz monzonorite. Chemically, they are tholeiitic and can be divided into two groups: a high-Mg group (6.2–22.9 wt.% MgO) and a relatively low-Mg group (2.2–5.7 wt.% MgO). The high-Mg group shows negative Eu-anomalies (Eu/Eu* = 0.53–0.72), slight light rare earth element enrichment (La/Yb_N = 0.56–1.53), and small negative anomalies in high field-strength elements. The ?Nd (t = 1.93 Ga) values vary from +0.3 to +2.4. The low-Mg group shows varied Eu-anomalies (Eu/Eu* = 0.48–1.05), and is enriched in light rare earth elements (La/Yb_N = 1.51–11.98). The majority shows negative anomalies in high field-strength elements (e.g., Th, Nb, Zr, and Ti). Initial ?Nd (at 1.93 Ga) values for low-Mg gabbronorites vary from −5.0 to 0. The Xuwujia gabbronorites possibly experienced assimilation of crust, and fractional crystallization of initially olivine and hypersthene (the high-Mg group), and then olivine, clinopyroxene, and plagioclase (the low-Mg group). The slightly younger Liangcheng granitoids consist of garnet-bearing granite, granodiorite and quartz-rich granitic compositions. They are intermediate to felsic calc-alkaline rocks, thought to be derived from surrounding metasedimentary crust. Xigou gabbro could represent early cumulates. The granitoids have relatively high-Mg numbers (up to 54), and show some chemical affinities with the gabbronorites, which could have resulted from incorporation of gabbronoritic melts. The occurrence and chemical variations of the Xuwujia gabbronorites and Liangcheng granitoids can be interpreted to have resulted from crust–mantle interaction, with mingling and partial mixing of mantle (gabbronoritic) and crustal (granitic) melts. The Xuwujia gabbronorites originated from a mantle region with high potential temperatures (∼1550 °C), possibly associated with a plume or more likely a ridge-subduction-related mantle upwelling event. They could have had extremely high primary intrusion temperatures (up to 1400 °C). Emplacement of these magmas was likely responsible for the extensive crustal anatexis (Liangcheng granitoids) and the local ultra-high-temperature metamorphism. These sequences may have followed ca. 1.95 Ga continent–continent (arc?) juxtaposition and were themselves followed by significant regional uplift and exhumation in the northern margin of the North China craton.  相似文献   

氯化法钛白粉生产项目放射性环境影响评价     

邱国华 《铀矿地质》2010,26(3):178-186

在放射性核素走向分析和环境现状调查的基础上,对某氯化法钛白粉生产项目的放射性环境影响进行了分析、预测与评价。放射性环境现状调查表明,评价因子总体在区域环境本底范围内,经分析确定了放射性敏感点。经放射性环境影响预测,工作人员和公众所受的附加剂量分别为0.59mSv/a和9.28×10-4mSv/a,均低于年有效剂量管理限值。在落实辐射防护和环境保护措施并加强放射性环境监测后,该项目的放射性环境影响符合国家有关法规和标准限值要求。  相似文献   

农田排水沟渠的环境效应与生态功能综述   总被引：9，自引：0，他引：9       下载免费PDF全文

陆海明  孙金华  邹鹰  朱乾德  丰华丽 《水科学进展》2010,21(5):719-725

农田排水沟渠作为农业景观中重要的景观单元,能够调节农田生态系统水分平衡,改变流域水文情势。农田养分可以随排水过程迅速流失,也可以通过沉淀与吸附机制被农田沟渠所截留或者通过植物吸收后收割与反硝化去除等机制脱离农田生态系统。作为农田生态系统边缘的交错带,农田排水沟渠较高的植物多样性可以提供动物栖息地和避难场所,增加农田生态系统生物多样性。清淤、收割和控制排水等管理措施对于农田排水沟渠的环境效应和生态服务功能有着不同的影响。今后应加强从多个学科研究农田排水沟渠的环境效应和生态功能,探索生态排水沟渠的构建和管理技术,实现农田排水沟渠水利功能和生态功能的"双赢"。  相似文献   

SH25H型液压风动冲击钻机在大口径硬岩钻孔灌注桩施工中的试验研究     

何龙飞  林坚  孙亚军  王宇清 《探矿工程》2010,37(8):41-43,46

根据京沪高速铁路徐州东站大口径嵌岩灌注桩工程,试制SH25H型液压风动冲击钻机？采用气动潜孔锤空气正循环组合钻进工艺,结合捞砂桶排渣,摸索总结出一套针对硬岩地层的干式成孔新方法,钻进效率及钻孔质量显著提高,为大直径成孔施工增添了一种新的方法。  相似文献   

青藏高原拉萨地体北部的前寒武纪变质作用及构造意义   总被引：12，自引：0，他引：12  

张泽明  董昕  耿官升  王伟  于飞  刘峰 《地质学报》2010,84(4):449-456

青藏高原南部拉萨地体中分布的角闪岩相至麻粒岩相变质岩一直被认为是前寒武纪变质基底,但并没有获得可靠的年代学证据。本文运用原位锆石U-Pb定年方法,在拉萨地体北部那果地区的变质岩中获得了约720Ma的变质年龄,从而证明拉萨地体北部在新古元代经历了角闪岩相变质作用和近同期的岩浆作用。基于这一成果和在拉萨地体中、南部高级变质岩中陆续获得的中、新生代变质年龄,对拉萨地体变质作用的时、空变化及其成因进行了初步探讨。  相似文献   

New insights into hominin lithic activities at FLK North Bed I, Olduvai Gorge, Tanzania     

F. Diez-Martin  P. Sanchez Yustos  M. Domínguez-Rodrigo  A.Z.P. Mabulla  H.T. Bunn  G.M. Ashley  R. Barba  E. Baquedano   《Quaternary Research》2010,74(3):376-387

Recent work at FLK North (FLK N) has unearthed a new archaeological assemblage recovered with precise control of its stratigraphic position. In the present work, the technological study of the new lithic sample is described. The results show the co-occurrence in the same site of different technological behaviors. At FLK N, hominins were involved in both percussion/battering activities and, through freehand and bipolar knapping, in core reduction. However, the reconstruction of the operational sequences shows that core reduction was probably a marginal behavior, while percussion/battering activities occurred more regularly throughout the sequence. If hominins were not involved in regular carcass processing, as recent taphonomic studies suggest, then hominins' sporadic and low-impact visits to the site over a long period of time must have been driven by other activities probably linked to the exploitation of alternative resources. Plant processing could have been a plausible explanation for hominin presence at FLK N.  相似文献   

Alpine tectono‐metamorphic history of the continental units from Vardar zone: the Kopaonik Metamorphic Complex (Dinaric‐Hellenic belt,Serbia)     

Mario Zelic  Nicola Levi  Alessandro Malasoma  Michele Marroni  Luca Pandolfi  Branislav Trivic 《Geological Journal》2010,45(1):59-77

The easternmost zone of the Dinaric‐Hellenic belt is represented by the Vardar Zone, in which the Kopaonik Metamorphic Complex (KMC) is regarded as the lowermost unit. This complex is topped by the unmetamorphosed Brzece unit and is intruded by the Oligocene Kopaonik Intrusive complex. The KMC is characterized by a stratigraphy that includes metapelites and meta‐carbonates of Late Triassic age, associated with metabasites. It is characterized by a complex deformation history that comprises four phases: D1 to D4. The D1 phase structures occur only as relict structures, whereas the D2 phase structures are represented by isoclinal F2 folds, associated with a well‐developed S2 foliation. The estimated P‐T conditions for the D1 and D2 metamorphism are consistent with the upper greenschist facies. The D3 phase is characterized by west‐verging thrusts associated with upright folds. In contrast, the D4 phase is characterized by open folds (F4) associated with low‐angle normal faults. The D1 and D2 deformation phases developed during the shortening related to continental collision, whereas the subsequent D3 and D4 phases can be related to the progressive exhumation of the KMC. The D4 phase probably developed during extensional tectonics during and after emplacement of the Kopaonik Intrusive Complex. The data show that the continental units belonging to the Vardar zone had a long‐lived deformation history that was more complex that previously thought. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Petrology, Mineralogy and Geochemisty of Antarctic Mesosiderite GRV 020175: Implications for Its Complex Formation History     

WANG Linyan  HSU Weibiao  and MA Changqian 《《地质学报》英文版》2010,84(3):528-542

<正>GRV 020175 is an Antarctic mesosiderite,containing about 43 vol%silicates and 57 vol% metal.Metal occurs in a variety of textures from irregular large masses,to veins penetrating silicates, and to matrix fine grains.The metallic portion contains kamacite,troilite and minor taenite.Terrestrial weathering is evident as partial replacement of the metal and troilite veins by Fe oxides.Silicate phases exhibit a porphyritic texture with pyroxene,plagioclase,minor silica and rare olivine phenocrysts embedded in a fine-grained groundmass.The matrix is ophitic and consists mainly of pyroxene and plagioclase grains.Some orthopyroxene phenocrysts occur as euhedral crystals with chemical zoning from a magnesian core to a ferroan overgrowth;others are characterized by many fine inclusions of plagioclase composition.Pigeonite has almost inverted to its orthopyroxene host with augite lamellae, enclosed by more magnesian rims.Olivine occurs as subhedral crystals,surrounded by a necklace of tiny chromite grains(about 2-3μm).Plagioclase has a heterogeneous composition without zoning. Pyroxene geothermometry of GRV 020175 gives a peak metamorphic temperature(～1000℃) and a closure temperature(～875℃).Molar Fe/Mn ratios(19-32) of pyroxenes are consistent with mesosiderite pyroxenes(16-35) and most plagioclase compositions(An_(87.5_96.6)) are within the range of mesosiderite plagioclase grains(An_(88-95)).Olivine composition(Fo_(53.8)) is only slightly lower than the range of olivine compositions in mesosiderites(Fo_(55-90)).All petrographic characteristics and chemical compositions of GRV 020175 are consistent with those of mesosiderite and based on its matrix texture and relatively abundant plagioclase,it can be further classified as a type 3A mesosiderite.Mineralogical, penological,and geochemical studies of GRV 020175 imply a complex formation history starting as rapid crystallization from a magma in a lava flow on the surface or as a shallow intrusion.Following primary igneous crystallization,the silicate underwent varying degrees of reheating.It was reheated to 1000℃,followed by rapid cooling to 875℃.Subsequently,metal mixed with silicate,during or after which,reduction of silicates occurred;the reducing agent is likely to have been sulfur.After redox reaction,the sample underwent thermal metamorphism,which produced the corona on the olivine, rims on the inverted pigeonite phenocrysts and overgrowths on the orthopyroxene phenocrysts,and homogenized matrix pyroxenes.Nevertheless,metamorphism was not extensive enough to completely reequilibrate the GRV 020175 materials.  相似文献